Environmental, Health, and Safety Guidelines
PULP AND PAPER MILLS
D
ECEMBER
10,
2007
3
WORLD BANK GROUP
•
Dry debarking of wood;
•
Systems for collection and recycling of temporary and
accidental discharges from process water spills;
•
Sufficient and balanced volumes of pulp storage, broke
storage and white water storage tanks to avoid or reduce
process water discharges;
•
Recycling of wastewater, with or without simultaneous
recovery of fibers (using filters or flotation plants);
•
Separation of contaminated and non-contaminated (clean)
wastewaters with collection and reuse of clean non-contact
cooling waters and sealing waters;
•
Potentially contaminated stormwater includes runoff from
log and wood handling areas, process equipment, building
roofs and areas immediately around the mill process areas.
This should be combined with process effluent for
treatment.
Guidance applicable to the management of cooling water, and
additional guidance applicable to stormwater, is presented in the
General EHS Guidelines.
Wastewater Management – Kraft and Sulfite Pulp Mills
Additional recommended wastewater prevention and control
methods for Kraft and sulfite mills include the following:
•
Oxygen delignification ahead of the bleach plant;
•
Efficient washing of the pulp ahead of the bleaching (Kraft
and sulfite mills);
•
Decreasing or eliminating the formation of 2,3,7,8-TCDD
and 2,3,7,8-TCDF in wood and non-wood bleaching
processes by
4
:
o
Replacement of elemental chlorine bleaching with
elemental chlorine free (ECF) bleaching
5
or total
chlorine free (TCF) bleaching
4
UNEP, 2006.
o
Reducing application of elemental chlorine by
decreasing chlorine multiple or increasing the
substitution of chlorine dioxide for molecular chlorine
o
Minimizing precursors such as dibenzo-p-dioxin and
dibenzofuran entering the bleach plant by using
precursor-free additives and thorough washing;
o
Maximize knot removal
o
Eliminating pulping of furnish contaminated with
polychlorinated phenols
•
Removal of hexenuronic acids by mild hydrolysis for
hardwood pulp, especially eucalyptus;
•
Collection and recycling of spent cooking liquor spills;
•
Stripping and reuse of evaporation and digester
condensates in order to reduce odor producing total
reduced sulfur (TRS) compounds (Kraft and sulfite mills).
•
Neutralization of spent cooking liquor before evaporation
and reuse of condensate in order to reduce dissolved
organics (Sulfite mills);
•
Including chemical recovery in sulfite as well as Kraft mills.
Wastewater Management – Mechanical and Chemi-
mechanical Mills
Additional recommended wastewater prevention and control
methods for mechanical and chemi-mechanical mills include the
following:
•
Minimizing reject losses;
•
Maximizing water recirculation in mechanical pulping
process;
•
Application of thickeners to effectively separate water
systems from the pulp and paper mills;
5
ECF bleaching requires on-site manufacture of chlorine dioxide (ClO
2
). The
ClO
2
process chosen should have low production of chlorine as a by -product of
ClO
2
production.