878
聚集,软包装电池不可避免的会发生胀气现象,这就会使原本
紧贴在一起的电极之间产生缝隙,从而增加了欧姆阻抗。
3 结论
使用经碳包覆法得到的磷酸铁锂材料为正极活性物质、
MCMB
为负极活性物质的电池,其在倍率放电、高低温性能和
循环寿命等方面都表现优异,证明了磷酸铁锂材料可以在动
力电池领域发挥本领。所以,只要对电极、电池等加以科学合
理的设计和不断的改进,磷酸铁锂材料一定可以在动力电池
领域得到更广泛的应用。
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能的影响。结果表明,该催化剂 600 ℃活化后在活性炭表面负
载更加均匀,无结晶现象;当Fe (Ⅱ) 的载量为 6%时,TDM-
NPPFe(
Ⅱ)在活性碳表面达到单层负载。所以 600 ℃活化的
6% Fe (
Ⅱ)载量的催化剂(Cat
max
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催化活性最好。把Cat
max
与
E-Tek
公司的 Pt/C 30%做了比较,Cat
max
的催化氧还原电子转
移数与 Pt/C 相近,即氧还原过程为 4 e 还原过程;耐甲醇测试
表明TDMNPPFe(Ⅱ)催化剂具有很好的耐甲醇性能。
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(
注:本文为第九届全国氢能学术会议论文)
(上接第 860 页)
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研 究 与 设 计
2009.10 Vol.33 No.10